Line a sheet pan with parchment paper. Set aside.
Place chocolate in a large microwave safe bowl and microwave in 30 second increments, stirring well after each, until chocolate is melted and smooth.
Spoon out desired amount of white chocolate and dollop onto prepared pan. Using the back of the spoon, drag the melted chocolate down into a curved shape. Repeat until you've achieve ghost-like figure.
Place in freezer to set.
Once set, take an edible marker and make little faces onto each ghost.
Place marshmallows in microwave safe bowl. Heat in 15 second increments, stirring after each, until melted and smooth.
Scoop out about 1 Tablespoon of melted marshmallow and, using your fingers, pull/stretch the marshmallow out to resemble a web-like pattern. Carefully place onto brownies, being sure to stretch it across to ensure it sticks.
Once you've gotten the desired amount of marshmallow onto the brownies, top with sprinkles.
Place white chocolate ghosts.